No, TAME has no scheduled flights out of Dublin. However, TAME does fly out of Luanda 4 de Fevereiro. There are also other airline options to choose from if you still want to book a flight from Dublin. Ethiopian Air, for example, is an airline that flies out of Dublin on a regular basis.
Catumbela is the most popular airport that TAME serves, followed by Soyo and Lubango.